In this work, the effect of composition to the electrochemical properties of spinel LiNio.sM1.504 (LNMO) was investigated. The cathode was prepared with a series of acetylene black:graphite contents 12.5:12.5; 10:10; 7.5:7.5; 5:5 and 2.5:2.5. The electrochemical properties were evaluated by Electrochemical Impedance Spectroscopy (EIS), Cyclic Voltammetry (CV) and Galvanostatic Cycling with Potential Limitation (GCPL). The optimized content 75% of LNMO could reduce charge transfer and reduce the barrier for Lt ion diffusion into the cathode.