Synthesis of new fluorinated imidazolium ionic liquids and their prospective function as the electrolytes for lithium-ion batteries

Abstract

Two fluorine-containing ionic liquids, 1-(2,2,2-trifluoroethyl)-3-methylimidazolium tosylate and 1-(2,2,2-trifluoroethyl)-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (TFSI anion), were obtained in good yields and high purity via a green pathway procedure free of solvent and hazardous catalyst. The incorporation of CF3 moieties in imidazolium structure decreases the ILs TFSI melting point. The preliminary electrochemical results are very promising, a wide electrochemical stability up to 5.7 V vs Li+ /Li for the fluorinated imidazolium with TFSI anion. 

 
IF: 2.761

DOI: 10.1016/j.jfluchem.2014.05.005